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Stereoselective rearrangements with chiral hypervalent iodine reagents

Farid, Umar, Malmedy, Florence, Claveau, Romain, Albers, Lena and Wirth, Thomas 2013. Stereoselective rearrangements with chiral hypervalent iodine reagents. Angewandte Chemie - International Edition 52 (27) , pp. 7018-7022. 10.1002/anie.201302358

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Abstract

I likes rearrangements: Hypervalent iodine compounds can be used as environmentally friendly, mild, and selective reagents for highly enantioselective rearrangements of alkenes. For the first time, rearrangements to α-arylated ketones can be performed enantioselectively using lactic acid-based iodine(III) reagents.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: acetals; aryl migration; hypervalent iodine; rearrangement; stereoselective synthesis
Publisher: Wiley-Blackwell
ISSN: 1433-7851
Last Modified: 13 Oct 2019 02:39
URI: http://orca.cf.ac.uk/id/eprint/48529

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