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cis-Dichloridotetrakis(dimethyl sulfoxide-[kappa]O)chromium(III) chloride dimethyl sulfoxide monosolvate

Al-Najjar, Nada A., Al-Sudani, Abdul-Razak, Shanshal, Muthana A., Mousa, Falih H. and Kariuki, Benson 2013. cis-Dichloridotetrakis(dimethyl sulfoxide-[kappa]O)chromium(III) chloride dimethyl sulfoxide monosolvate. Acta Crystallographica Section E - Structure Reports Online 69 (7) , m395. 10.1107/S160053681301622X

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The structure of the title compound, [CrCl2(C2H6OS)4]Cl·C2H6OS, consists of a CrIII ion coordinated by four O atoms of dimethyl sulfoxide (DMSO) ligands and two chloride ions in cis positions, forming a distorted CrCl2O4 octahedron. An isolated Cl- counter-anion and a positionally disordered DMSO molecule [occupancy ratio 0.654 (4):0.346 (4)] are also present. In the structure, the complex cations interact with the Cl- counter-anions and the DMSO solvent molecules via weak C-H...Cl and C-H...O interactions, forming a three-dimensional network.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: International Union of Crystallography
ISSN: 1600-5368
Last Modified: 04 Jun 2017 05:14

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