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Selective oxidation of glycerol with oxygen using mono and bimetallic catalysts based on Au, Pd and Pt metals

Bianchi, C. L., Canton, P., Dimitratos, Nikolaos, Porta, F. and Prati, L. 2005. Selective oxidation of glycerol with oxygen using mono and bimetallic catalysts based on Au, Pd and Pt metals. Catalysis Today 102-3 , pp. 203-212. 10.1016/j.cattod.2005.02.003

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Abstract

The liquid phase oxidation of glycerol with oxygen has been studied using a series of monometallic and bimetallic catalysts based on Au, Pd and Pt metals supported on carbon, in order to study the effect of the metal on the distribution of the products. It was found that by using bimetallic catalysts (Au–Pd, Au–Pt) the distribution of the products could be controlled. Moreover, bimetallic catalysts were by far more active than monometallic catalysts. Selectivity could be tuned by using different preparation method.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Glyceric acid; Glycolic acid; Tartronic acid; Liquid-phase oxidation of glycerol; Gold; Palladium; Platinum
Publisher: Elsevier
ISSN: 0920-5861
Last Modified: 04 Jun 2017 05:44
URI: http://orca.cf.ac.uk/id/eprint/53103

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