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Novel chiral hypervalent iodoarenes in enantioselective iodocatalysis and oxidation reactions

Altermann, Sabine 2008. Novel chiral hypervalent iodoarenes in enantioselective iodocatalysis and oxidation reactions. PhD Thesis, Cardiff University.

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Abstract

A range of enantiomerically pure iodine compounds has been synthesised and either oxidised to the corresponding hypervalent iodine compound and used as oxidant or employed as catalysts in a range of reactions together with different oxidants in stoichiometric amounts in order to form the respective hypervalent iodine species in situ. Three different enantioselective catalytic reactions have been investigated: cc-acetoxylation of ketones, halolactonisation of pentenoic acids and oc-oxytosylation of ketones. Also - probably for the first time - alkyliodides have been employed as catalysts in these transformations.

Item Type: Thesis (PhD)
Status: Unpublished
Schools: Chemistry
Subjects: Q Science > QD Chemistry
ISBN: 9781303213823
Date of First Compliant Deposit: 30 March 2016
Last Modified: 15 Jan 2019 16:09
URI: http://orca.cf.ac.uk/id/eprint/54769

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