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A two-coordinate manganese(0) complex with an unsupported mn-mg bond: allowing access to low coordinate homo- and heterobimetallic compounds

Hicks, Jamie, Hoyer, Chad E., Moubaraki, Boujemaa, Manni, Giovanni Li, Carter, Emma, Murphy, Damien M., Murray, Keith S., Gagliardi, Laura and Jones, Cameron 2014. A two-coordinate manganese(0) complex with an unsupported mn-mg bond: allowing access to low coordinate homo- and heterobimetallic compounds. Journal of the American Chemical Society 136 (14) , pp. 5283-5286. 10.1021/ja5021348

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Abstract

This study details the synthesis and characterization of an unprecedented two-coordinate, high-spin manganese(0) complex that incorporates an unsupported Mn–Mg bond, viz. L†MnMg(MesNacnac) (L† = −N(Ar†)(SiPri3), Ar† = C6H2{C(H)Ph2}2Pri-2,6,4; MesNacnac = [(MesNCMe)2CH]−; Mes = mesityl). This compound has been utilized as an “inorganic Grignard reagent” in the preparation of the first two-coordinate manganese(I) dimer, L†MnMnL* (L* = −N(Ar*)(SiMe3), Ar* = C6H2{C(H)Ph2}2Me-2,6,4), and the related mixed valence, bis(amido)-hetereobimetallic complex, MnII(μ-L†)(μ-L*)Cr0. It is also shown to act as a two-electron reducing agent in reactions with unsaturated substrates.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 0002-7863
Funders: EPSRC
Last Modified: 17 Jun 2019 02:46
URI: http://orca.cf.ac.uk/id/eprint/64770

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