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An unexpected dependence on the SnII base; reactions of Sn(NR2)2 with aromatic dithiols

Melen, Rebecca L., McPartlin, Mary and Wright, Dominic S. 2011. An unexpected dependence on the SnII base; reactions of Sn(NR2)2 with aromatic dithiols. Dalton Transactions 40 (8) , pp. 1649-1651. 10.1039/c0dt01690j

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Abstract

Unexpectedly, the reactions of the SnII base Sn(NMe2)2 with 1,2-benzodithiols [L(SH)2] do not give the stannylenes, L(S)2Sn, which are generated with Sn{N(SiMe3)2}2, instead the ion-separated SnIV compounds [Sn{L(S)2}]2−2[R2NH2]+ are formed in high yields.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Date of Acceptance: 5 January 2011
Last Modified: 04 Jun 2017 06:49
URI: http://orca.cf.ac.uk/id/eprint/65052

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