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Formation of N-bridgehead 1,2,5-thiadiazolium and selenadiazolium rings through an intramolecular cyclisation reaction

Bacon, Catherine E., Eisler, Dana J., Melen, Rebecca L. and Rawson, Jeremy M. 2008. Formation of N-bridgehead 1,2,5-thiadiazolium and selenadiazolium rings through an intramolecular cyclisation reaction. Chemical Communications 40 , pp. 4924-4926. 10.1039/b809987a

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Abstract

Treatment of N-lithiopyridylketimide derivatives Li[R(C = N)py] (R = Ph, py) with ECl2 (E = S, Se) affords the fused thiadiazolium and selenadiazolium salts [RC6H4N2E]Cl [1]Cl and [2]Cl containing a bridgehead N atom through intramolecular coordination.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 1359-7345
Date of Acceptance: 11 August 2008
Last Modified: 04 Jun 2017 06:49
URI: http://orca.cf.ac.uk/id/eprint/65059

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