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Photoinduced energy transfer in a conformationally flexible Re(I)/Ru(II) dyad probed by time-resolved infrared spectroscopy: Effects of conformation and spatial localization of excited states

Easun, Timothy, Alsindi, Wassim Z., Towrie, Michael, Ronayne, Kate L., Sun, Xue-Zhong, Ward, Michael D. and George, Michael W. 2008. Photoinduced energy transfer in a conformationally flexible Re(I)/Ru(II) dyad probed by time-resolved infrared spectroscopy: Effects of conformation and spatial localization of excited states. Inorganic Chemistry 47 (12) , pp. 5071-5078. 10.1021/ic702005w

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Abstract

A combination of luminescence and picosecond- and nanosecond-time-scale time-resolved IR studies has been used to eludicate the photophysical behavior of the dyad RuLRe, in which a combination of (i) different conformations of the flexible bridging ligand and (ii) different 3MLCT states on the RuII acceptor leads to the presence of several different Re → Ru energy-transfer rates being identified.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 0020-1669
Last Modified: 04 Jun 2017 07:58
URI: http://orca.cf.ac.uk/id/eprint/71025

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Cited 31 times in Web of Science. View in Web of Science.

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