Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Regiodivergent Lewis base-promoted O- to C-carboxyl transfer of furanyl carbonates

Campbell, Craig D., Joannesse, Caroline, Morrill, Louis, Philp, Douglas and Smith, Andrew D. 2015. Regiodivergent Lewis base-promoted O- to C-carboxyl transfer of furanyl carbonates. Organic & Biomolecular Chemistry 13 (10) , pp. 2895-2900. 10.1039/C4OB02629B

Full text not available from this repository.

Abstract

Triazolinylidenes promote γ-selective C-carboxylation (up to 99:1 regioselectivity) in the O- to C-carboxyl transfer of furanyl carbonates in contrast to DMAP that promotes preferential α-C-carboxylation with moderate regiocontrol (typically 60:40 regioselectivity). The generality of this process is described and a simple mechanistic and kinetic model postulated to account for the observed regioselectivity.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Additional Information: First published online 3 February 2015
Publisher: Royal Society of Chemistry
ISSN: 1477-0520
Date of Acceptance: 16 January 2015
Last Modified: 04 Jun 2017 08:12
URI: http://orca.cf.ac.uk/id/eprint/74300

Citation Data

Cited 2 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item