Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Petrogenesis of the ∼2·77 Ga Monts de Cristal Complex, Gabon: Evidence for Direct Precipitation of Pt-arsenides from Basaltic Magma

Maier, Wolfgang D., Rasmussen, B., Fletcher, I. R., Godel, B., Barnes, S. J., Fisher, L. A., Yang, S. H., Huhma, H. and Lahaye, Y. 2015. Petrogenesis of the ∼2·77 Ga Monts de Cristal Complex, Gabon: Evidence for Direct Precipitation of Pt-arsenides from Basaltic Magma. Journal of Petrology 56 (7) , pp. 1285-1308. 10.1093/petrology/egv035

[img]
Preview
PDF - Accepted Post-Print Version
Download (1MB) | Preview

Abstract

The Monts de Cristal Complex of Gabon consists of several igneous bodies interpreted to be remnants of a tectonically dismembered, >100 km long and 1–3 km wide, ultramafic–mafic intrusion emplaced at 2765–2775 Ma. It is the most significant mafic–ultramafic layered complex yet identified on the Congo Craton. The complex consists largely of orthopyroxenite cumulates, with less abundant olivine-orthopyroxenite and norite, and rare harzburgite and dunite. Mineral compositions (Fool 84, Mg#Opx 85, Anplag 60–68, Cr/Fe chromite 1–1·45) and whole-rock data suggest that the parent magma was a low-Ti basalt containing approximately 10% MgO and 0·5% TiO2. Trace element and Rb–Sr and Sm–Nd isotope data indicate the presence of an enriched component, possibly derived from crustal contamination of a magma generated in the sub-lithospheric mantle. Most rocks show a highly unusual pattern of strong Pt enrichment (10–150 ppb) at low concentrations of Pd (1–15 ppb), Au (1–2 ppb), Cu (1–20 ppm), and S (<500 ppm), suggesting that unlike in most other PGE-rich intrusions globally, platinum in the Monts de Cristal Complex is not hosted in magmatic sulfides. Synchrotron X-ray fluorescence mapping has revealed the location of buried small Pt particles, most of which are associated with As. We propose that this constitutes some of the strongest evidence yet in support of magmatic crystallization of a Pt–As phase from S-undersaturated magma.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Earth and Ocean Sciences
Publisher: Oxford Journal
ISSN: 0022-3530
Date of First Compliant Deposit: 30 March 2016
Date of Acceptance: 16 June 2015
Last Modified: 01 Jul 2019 16:44
URI: http://orca.cf.ac.uk/id/eprint/81604

Citation Data

Cited 14 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item

Downloads

Downloads per month over past year

View more statistics