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Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study

O'Connor, Alice E, Mirzadeh, Nedaossadat, Bhargava, Suresh K, Easun, Timothy, Schroder, M. and Blake, Alexander J. 2016. Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study. Chemical Communications- Royal Society of Chemistry 52 , pp. 6769-6772. 10.1039/C6CC00923A

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Abstract

High pressure crystallographic studies on [1,4-C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveals the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Date of First Compliant Deposit: 30 March 2016
Date of Acceptance: 11 March 2016
Last Modified: 04 Jun 2017 08:55
URI: http://orca.cf.ac.uk/id/eprint/87890

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