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Synthesis of tertiary enamides by Ag2CO3-promoted Pd-catalyzed alkenylation of acyclic secondary amides

Delforge, Arnaud, Georgiou, Irene, Kremer, Adrian, Wouters, Johan and Bonifazi, Davide 2016. Synthesis of tertiary enamides by Ag2CO3-promoted Pd-catalyzed alkenylation of acyclic secondary amides. Organic Letters 18 (19) , pp. 4844-4847. 10.1021/acs.orglett.6b02305

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Abstract

A Pd-catalyzed methodology for the preparation of tertiary enamides from acyclic secondary amides and bromo acrylates under mild reaction conditions has been developed using [Pd2(dba)3], XantPhos, and Ag2CO3 as a base. The reaction occurs through a stereospecific metal-mediated oxidative-insertion mechanism.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Publisher: American Chemical Society
ISSN: 1523-7060
Date of First Compliant Deposit: 3 October 2016
Date of Acceptance: 20 September 2016
Last Modified: 11 Dec 2018 16:30
URI: http://orca.cf.ac.uk/id/eprint/95046

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