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Highly efficient ethylene polymerisation by scandium alkyls supported by neutral fac-kappa(3) coordinated N-3 donor ligands

Lawrence, S. C., Ward, Benjamin David, Dubberley, S. R., Kozak, C. M. and Mountford, P. 2003. Highly efficient ethylene polymerisation by scandium alkyls supported by neutral fac-kappa(3) coordinated N-3 donor ligands. Chemical Communications (23) , pp. 2880-2881. 10.1039/B310867H

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Abstract

Reaction of [M(CH2SiMe3)3(THF)2] (M = Sc or Y) with the neutral fac-κ3 N3 donor ligands (L) Me3[9]aneN3 or HC(Me2pz)3 gave the corresponding trialkyls [M(L)(CH2SiMe3)3]; activation of the scandium congeners with B(C6F5)3 in the presence of ethylene afforded highly active polymerisation catalysts (Me3[9]aneN3 = 1,4,7-trimethyltriazacyclononane).

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 1359-7345
Last Modified: 04 Jun 2017 02:08
URI: http://orca.cf.ac.uk/id/eprint/9712

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