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A new diamido-amine ligand based on three-carbon atom "arms": synthesis, structures and polymerisation capability of zirconium derivatives of MeN(CH2CH2CH2NSiMe3)(2)

Lowes, T. A., Ward, Benjamin David, Whannel, R. A., Dubberley, S. R. and Mountford, P. 2005. A new diamido-amine ligand based on three-carbon atom "arms": synthesis, structures and polymerisation capability of zirconium derivatives of MeN(CH2CH2CH2NSiMe3)(2). Chemical Communications- Royal Society of Chemistry (1) , pp. 113-115. 10.1039/B412381F

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Abstract

Zirconium compounds of the new diamido-amine ligand MeN(CH2CH2CH2NSiMe3)2 feature significantly different molecular structures and considerably improved olefin polymerisation characteristics in comparison with analogous compounds based on the two-carbon arm homologues.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Last Modified: 04 Jun 2017 02:08
URI: http://orca.cf.ac.uk/id/eprint/9715

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