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Catalytic use of selenium electrophiles in cyclizations

Browne, Danielle Michelle, Niyomura, Osamu and Wirth, Thomas 2007. Catalytic use of selenium electrophiles in cyclizations. Organic Letters 9 (16) , pp. 3169-3171. 10.1021/ol071223y

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Abstract

A new and convenient one-pot method for a catalytic addition-elimination reaction using selenium electrophiles has been developed. In the presence of 5 mol % diphenyl diselenide, [bis(trifluoroacetoxy)iodo]benzene in acetonitrile converted a range of (E)-3-butenoic acids into the corresponding butenolides in good yields.

Item Type: Article
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Butenolides; Iodosobenzene bis(trifluoroacetate)
Publisher: American Chemical Society
ISSN: 1523-7060
Last Modified: 04 Jun 2017 02:08
URI: http://orca.cf.ac.uk/id/eprint/9773

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