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The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

Martin, Adam D., Easun, Timothy, Argent, Stephen P., Lewis, William, Blake, Alexander J. and Schröder, Martin 2017. The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene. Crystengcomm 19 (4) , pp. 603-607. 10.1039/C6CE01965J

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Abstract

Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However, the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1466-8033
Funders: EPSRC, ERC and Royal Society
Date of First Compliant Deposit: 6 February 2017
Date of Acceptance: 1 October 2016
Last Modified: 04 Jun 2017 09:40
URI: http://orca.cf.ac.uk/id/eprint/98094

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