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The oxidative dehydrogenation of propane using gallium-molybdenum based catalysts

Davies, Thomas and Taylor, Stuart H. ORCID: https://orcid.org/0000-0002-1933-4874 2004. The oxidative dehydrogenation of propane using gallium-molybdenum based catalysts. Catalysis Letters 93 (3-4) , pp. 151-154. 10.1023/B:CATL.0000017069.52359.6a

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Abstract

Catalysts based on a physical mixture of Ga2O3 and MoO3 have been prepared and evaluated for propane partial oxidation to propene. The Ga2O3/MoO3 catalysts demonstrated propene yields greater than a 6 wt V2O 5/TiO2 catalyst, which is known to be active for the reaction. The higher yield of propene was achieved by the alkane activation properties of Ga2O3 and the selective oxidation function of MoO3 combining in a synergistic manner.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Calcination; Catalyst selectivity; Chemical bonds; Dehydrogenation; Gallium compounds; Molybdenum compounds; Oxidation; Propane; Propylene; Raman spectroscopy; Rate constants; Thermodynamics; X ray diffraction analysis, Gallium oxides; Molybdenum oxides; Partial oxidation; Selective oxidation, Catalyst activity
Additional Information: cited By (since 1996) 6
Publisher: Springer
ISSN: 1011-372X
Last Modified: 17 Aug 2023 01:05
URI: https://orca.cardiff.ac.uk/id/eprint/10289

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