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Simple Polyphenyl Zirconium and Hafnium Metallocene Room-Temperature Lumophores for Cell Imaging

Pritchard, Victoria E., Thorp-Greenwood, Flora Lottie, Balasingham, Rebeca, Williams, Catrin Ffion ORCID: https://orcid.org/0000-0001-8619-2581, Kariuki, Benson ORCID: https://orcid.org/0000-0002-8658-3897, Platts, James Alexis ORCID: https://orcid.org/0000-0002-1008-6595, Hallett, Andrew Jon and Coogan, Michael Peter 2013. Simple Polyphenyl Zirconium and Hafnium Metallocene Room-Temperature Lumophores for Cell Imaging. Organometallics 32 (12) , pp. 3566-3569. 10.1021/om400212y

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Abstract

Zirconium and hafnium metallocene dihalides based on simple polyphenyl cyclopentadienes are stable room-temperature lumophores with large Stokes shifts, emitting from states with substantial LMCT character. Their synthesis is described, including by a rapid solvent-free approach compatible with the lifetime of PET-active isotopes (89Zr). Preliminary experiments indicate the viability of these species as lumophores for fluorescence cell-imaging microscopy.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Advanced Research Computing @ Cardiff (ARCCA)
Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 0276-7333
Last Modified: 10 Nov 2022 13:34
URI: https://orca.cardiff.ac.uk/id/eprint/48691

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