Oxidation of benzyl alcohol and carbon monoxide using gold nanoparticles supported on MnO2 nanowire microspheres

Alhumaimess, Mosaed, Lin, Zhongjie, He, Qian ORCID: https://orcid.org/0000-0003-4891-3581, Lu, Li, Dimitratos, Nickolaos ORCID: https://orcid.org/0000-0002-6620-4335, Dummer, Nicholas F. ORCID: https://orcid.org/0000-0002-0946-6304, Conte, Marco, Taylor, Stuart H. ORCID: https://orcid.org/0000-0002-1933-4874, Bartley, Jonathan K. ORCID: https://orcid.org/0000-0003-4640-541X, Kiely, Christopher J. ORCID: https://orcid.org/0000-0001-5412-0970 and Hutchings, Graham J. ORCID: https://orcid.org/0000-0001-8885-1560 2014. Oxidation of benzyl alcohol and carbon monoxide using gold nanoparticles supported on MnO2 nanowire microspheres. Chemistry - A European Journal 20 (6) , pp. 1701-1710. 10.1002/chem.201303355

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Abstract

MnO2 was synthesised as a catalyst support material using a hydrothermal method. This involved reacting MnSO4⋅H2O and (NH4)2S2O8 at 120 °C for a range of crystallisation times, which affords control over the morphology and phase composition of the MnO2 formed. Gold was deposited on these supports using sol-immobilisation, impregnation and deposition precipitation methods, and the resultant materials were used for the oxidation of benzyl alcohol and carbon monoxide. The effect of the support morphology on the dispersion of the gold nanoparticles and the consequent effect on the catalytic performance is described and discussed.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Uncontrolled Keywords:	Benzyl alcohol oxidation; CO oxidation; gold catalysis; heterogeneous catalysis; nanomaterials.
Publisher:	Wiley
ISSN:	0947-6539
Date of First Compliant Deposit:	25 October 2016
Date of Acceptance:	8 January 2014
Last Modified:	05 Apr 2024 20:03
URI:	https://orca.cardiff.ac.uk/id/eprint/65719

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