Extended O-doped polycyclic aromatic hydrocarbons

Stassen, Daphné, Demitri, Nicola and Bonifazi, Davide ORCID: https://orcid.org/0000-0001-5717-0121 2016. Extended O-doped polycyclic aromatic hydrocarbons. Angewandte Chemie - International Edition 55 (20) , pp. 5947-5951. 10.1002/anie.201509517

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Abstract

The synthesis of O-doped benzorylenes, in which peripheral carbon atoms have been replaced by oxygen atoms, has been achieved for the first time. This includes key high-yielding ring-closure steps which, through intramolecular C−O bond formation, allow stepwise planarization of oligonaphthalenes. Single-crystal X-ray diffraction showed that the tetraoxa derivative forms remarkable face-to-face π–π stacks in the solid state, a favorable solid-state arrangement for organic electronics.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Wiley-Blackwell
ISSN:	1433-7851
Funders:	ERC Project reference: 280183
Date of First Compliant Deposit:	13 April 2016
Date of Acceptance:	24 March 2016
Last Modified:	06 Jan 2024 04:47
URI:	https://orca.cardiff.ac.uk/id/eprint/89195

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