Delforge, Arnaud, Georgiou, Irene, Kremer, Adrian, Wouters, Johan and Bonifazi, Davide ORCID: https://orcid.org/0000-0001-5717-0121 2016. Synthesis of tertiary enamides by Ag2CO3-promoted Pd-catalyzed alkenylation of acyclic secondary amides. Organic Letters 18 (19) , pp. 4844-4847. 10.1021/acs.orglett.6b02305 |
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Official URL: http://dx.doi.org/10.1021/acs.orglett.6b02305
Abstract
A Pd-catalyzed methodology for the preparation of tertiary enamides from acyclic secondary amides and bromo acrylates under mild reaction conditions has been developed using [Pd2(dba)3], XantPhos, and Ag2CO3 as a base. The reaction occurs through a stereospecific metal-mediated oxidative-insertion mechanism.
Item Type: | Article |
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Date Type: | Published Online |
Status: | Published |
Schools: | Chemistry |
Publisher: | American Chemical Society |
ISSN: | 1523-7060 |
Date of First Compliant Deposit: | 3 October 2016 |
Date of Acceptance: | 20 September 2016 |
Last Modified: | 06 Jan 2024 17:55 |
URI: | https://orca.cardiff.ac.uk/id/eprint/95046 |
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