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A neutral, monomeric germanium(I) radical

Woodul, William D., Carter, Emma, Müller, Robert, Richards, Anne F., Stasch, Andreas, Kaupp, Martin, Murphy, Damien Martin, Driess, Matthias and Jones, Cameron 2011. A neutral, monomeric germanium(I) radical. Journal of the American Chemical Society 133 (26) , pp. 10074-10077. 10.1021/ja204344e

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Stoichiometric reduction of the bulky β-diketiminato germanium(II) chloride complex [(ButNacnac)GeCl] (ButNacnac = [{N(Dip)C(But)}2CH]−, Dip = C6H3Pri2-2,6) with either sodium naphthalenide or the magnesium(I) dimer [{(MesNacnac)Mg}2] (MesNacnac = [(MesNCMe)2CH]−, Mes = mesityl) afforded the radical complex [(ButNacnac)Ge:]• in moderate yields. X-ray crystallographic, EPR/ENDOR spectroscopic, computational, and reactivity studies revealed this to be the first authenticated monomeric, neutral germanium(I) radical.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 0002-7863
Last Modified: 03 Jun 2020 15:25

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