Crystal structures, EPR and magnetic properties of 2-ClC6H4CNSSN˙ and 2,5-Cl2C6H3CNSSN˙

Alberola, Antonio, Carter, Emma ORCID: https://orcid.org/0000-0001-6691-2377, Constantinides, Christos P., Eisler, Dana J., Murphy, Damien Martin ORCID: https://orcid.org/0000-0002-5941-4879 and Rawson, Jeremy M. 2011. Crystal structures, EPR and magnetic properties of 2-ClC6H4CNSSN˙ and 2,5-Cl2C6H3CNSSN˙. Chemical Communications 47 (9) , pp. 2532-2534. 10.1039/c0cc04296j

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Abstract

The β-sheet structure associated with chlorinated aromatics (dClCl ≈ 4.0 Å) has been implemented to drive formation of π-stacked structures of dithiadiazolyl radicals. Both title compounds exhibit an increase in paramagnetism above 150 K but solid-state EPR studies indicate that the origin of the paramagnetism in these two systems is different.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	RSC Publishing
ISSN:	1359-7345
Last Modified:	03 Dec 2022 11:19
URI:	https://orca.cardiff.ac.uk/id/eprint/12966

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