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Simplifying iron-phosphine catalysts for cross-coupling reactions

Bedford, R. B., Carter, Emma, Cogswell, P. M., Gower, N. J., Haddow, M. F., Harvey, J. N., Murphy, Damien Martin, Neeve, E. C. and Nunn, J. 2013. Simplifying iron-phosphine catalysts for cross-coupling reactions. Angewandte Chemie - International Edition 52 (4) , pp. 1285-1288. 10.1002/anie.201207868

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Any old iron? Iron catalysts based on the widely available diphosphine ligand bis(diphenylphosphino)ethane have not previously fared particularly well in iron-catalyzed cross-coupling processes. However, this turns out not to be due to any inherently poor performance associated with the ligand, but rather the need to form a bis-chelate complex, either before or during the formation of an active FeI species.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: alkyl halides; catalysis; cross-coupling; iron; phosphine ligands
Publisher: Wiley-Blackwell
ISSN: 1521-3773
Funders: EPSRC
Last Modified: 13 May 2019 19:47

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